Template Synthesis of Porous Polypyrrole in 3D Coordination Nanochannels
Template Synthesis of Porous Polypyrrole in 3D Coordination Nanochannels
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DOI：
10.1021/cm901361m
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发表时间：
2009-08
影响因子：
8.6
通讯作者：
T. Uemura;Yu Kadowaki;N. Yanai;S. Kitagawa
中科院分区：
文献类型：
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作者：
T. Uemura;Yu Kadowaki;N. Yanai;S. Kitagawa
[Cu3(BTC)2]n（BTC = 苯-1,3,5-三羧酸酯）3D 纳米通道中吡咯的氧化聚合在框架内产生聚吡咯 (PPy)。随后通过在氨溶液中溶解主体框架来分离 PPy，得到功能性多孔 PPy，这与传统的本体合成 PPy 系统形成对比。
Oxidative polymerization of pyrrole in the 3D nanochannels of [Cu3(BTC)2]n (BTC = benzene-1,3,5-tricarboxylate) produced polypyrrole (PPy) inside the framework. Subsequent isolation of PPy by dissolution of the host framework in ammonia solution gave a functional porous PPy, which contrasts with the conventional bulk-synthesized PPy system.