Regioselective functionalization of alkanes by sequential dehydrogenation-hydrozirconation.
Regioselective functionalization of alkanes by sequential dehydrogenation-hydrozirconation.
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DOI：
10.1039/c0cc00243g
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发表时间：
2010-07
影响因子：
4.9
通讯作者：
Y. Kuninobu;Tomonari Ureshino;S. Yamamoto;K. Takai
中科院分区：
文献类型：
--
作者：
Y. Kuninobu;Tomonari Ureshino;S. Yamamoto;K. Takai
我们通过铱催化的烷烃脱氢、氢锆化和烷基锆中间体的亲电反应，成功地实现了烷烃的形式区域选择性功能化。
We have succeeded in formal regioselective functionalization of alkanes by iridium-catalyzed dehydrogenation, hydrozirconation of the resulting alkenes, and electrophilic reaction of the generated alkylzirconium intermediate.