Concise syntheses of strychnine and englerin A: the power of reductive cyclizations triggered by samarium iodide.
Concise syntheses of strychnine and englerin A: the power of reductive cyclizations triggered by samarium iodide.
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DOI：
10.1002/anie.201103128
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发表时间：
2011-08
影响因子：
--
通讯作者：
M. Szostak;D. Procter
中科院分区：
文献类型：
--
作者：
M. Szostak;D. Procter
电子：在电子转移试剂二碘化钐(卡根试剂)的引导下，壮观的环化反应有助于有效地合成经典生物碱士的宁和最近发现的愈创木倍半萜--英格列林A(见图)。
Electronica: Spectacular cyclization reactions mediated by the electron-transfer reagent samarium diiodide (Kagan's reagent) were instrumental in efficient syntheses of the classic alkaloid strychnine and the recently discovered guaiane sesquiterpene, englerin A (see picture).