Synthesis, chemistry, and crystal structures of high-valent transition-metal chalcogenide fluorides and their derivatives
Synthesis, chemistry, and crystal structures of high-valent transition-metal chalcogenide fluorides and their derivatives
复制标题
高价过渡金属硫系氟化物及其衍生物的合成、化学和晶体结构
DOI：
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发表时间：
1983
期刊：
影响因子：
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通讯作者：
D. Russell
中科院分区：
文献类型：
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作者：
J. Holloway;V. Kaučič;D. Russell
高产率制备了固体过渡金属硫系氟化物WF4S、WF4Se和ReF4S，并对其化学性质进行了研究；x射线晶体学表明，WF4S和ReF4S具有氟桥链结构，而WF4S·MeCN为单体。
The solid transition-metal chalcogenide fluorides, WF4S, WF4Se, and ReF4S have been prepared in high yield and their chemistry has been examined; X-ray crystallography has shown that WF4S and ReF4S have fluorine bridged polymeric chain structures whilst WF4S·MeCN is a monomer.