PREPARATION OF ACYCLIC ISOIMIDES AND THEIR REARRANGEMENT RATES TO IMIDES
PREPARATION OF ACYCLIC ISOIMIDES AND THEIR REARRANGEMENT RATES TO IMIDES
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DOI：
10.1021/jo00983a028
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发表时间：
1972-01-01
影响因子：
3.6
通讯作者：
SCHWARZ, JSP
中科院分区：
文献类型：
--
作者：
SCHWARZ, JSP
Rir 2河r2 a H Me d Me H B H H e Cl H c H Cl f H NO;用这种结构进行分子间酰化的可能性，制备一系列异酰亚胺2以研究形成的相对容易性并测量重排成酰亚胺3的速率。如果能抑制分子内重排速率，则可能发生分子间酰基转移。分子内的类似物已经被发现很多次，
Ri r2 R. r2 a H Me d Me H b H H e Cl H c H Cl f H NO; the possibility of carrying out intermolecular acylations with such a structure, a series of isoimides 2 were prepared to study the relative ease of formation and measure the rate of rearrangement to imide 3. If the intra-molecular rearrangement rate could be inhibited, inter-molecular acyl transfer might occur. Intramolecular analogies to this have been found many times when an