P-P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes
P-P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes
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DOI：
10.1039/c3cc38841g
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Roesky, Peter W.
中科院分区：
文献类型：
--
作者：
Li, Tianshu;Gamer, Michael T.;Roesky, Peter W.
用[Cp*Fe(eta(5)- p -5)]与三茂烯还原二聚化法制备了两种新的3d/4f多磷酸盐配合物[(Cp*Fe)(2)P-10{Sm-(eta(5)- c5me4r)(2)}(2)] （Cp* = eta 5- c5me5; R = Me, nPr）。它们是第一个P-10桥接3d/4f金属配合物，也是第一个用二价镧系元素还原偶联多磷酸盐配合物的例子。
The two new 3d/4f polyphosphide complexes [(Cp*Fe)(2)P-10{Sm-(eta(5)-C5Me4R)(2)}(2)] (Cp* = eta 5-C5Me5; R = Me, nPr) were prepared by reductive dimerization of [Cp*Fe(eta(5)-P-5)] with samarocenes. They are the first P-10 bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides.