THE LOCALIZATION MODEL OF RUBBER ELASTICITY .2.
THE LOCALIZATION MODEL OF RUBBER ELASTICITY .2.
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DOI：
10.1007/bf00419973
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发表时间：
1990-05-01
期刊：
影响因子：
3.2
通讯作者：
DOUGLAS, JF
中科院分区：
文献类型：
--
作者：
GAYLORD, RJ;DOUGLAS, JF
周围链对网络链的空间定位的影响被纳入链概率分布函数中，然后使用约束系统的统计力学形式计算网络自由能。除了具有经典“高斯”形式的项之外，所得表达式还包含另一个项，该项取决于网络的交联密度和未交联熔体的平台模量。
The effect of the spatial localization of a network chain by surrounding chains is incorporated into the chain probability distribution function and the network free energy is then calculated using the statistical mechanical formalism for constrained systems. In addition to a term having the classical ‘Gaussian’ form, the resulting expression contains another term which depends on both the cross-link density of the network and the plateau modulus of the uncross-linked melt.