Laser‐induced fluorescence of the C2H5O radical

Laser‐induced fluorescence of the C2H5O radical
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C2H5O 自由基的激光诱导荧光

DOI:
10.1063/1.442325
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发表时间:
1981
影响因子:
4.4
通讯作者:
H. Akimoto
H. Akimoto
中科院分区:
化学2区
文献类型:
--
作者:
G. Inoue;M. Okuda;H. Akimoto

文献摘要

被引文献

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报道了C2 H5 O自由基的激光激发和激光诱导荧光光谱。0-0乐队的?-?跃迁位于29 204 cm−1(342.4 nm)。光谱的特点是由一个突出的进展,涉及C-O伸缩模式,在CH 3 O自由基的情况下。基态和激发态的基本C-O伸缩频率分别为1067和596 cm−1。
Laser‐excitation and laser‐induced fluorescence spectra of the C2H5O radical are reported. The 0–0 band of the ?–? transition lies at 29 204 cm−1 (342.4 nm). The spectra are characterized by a prominent progression involving the C–O stretching mode, as in the case of the CH3O radical. The fundamental C–O stretching frequencies in the ground and excited states are 1067 and 596 cm−1, respectively.