Selective oxidation rapidly decomposes biomass-based activated carbons into graphite-like crystallites

Selective oxidation rapidly decomposes biomass-based activated carbons into graphite-like crystallites
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DOI:
10.1016/j.carbon.2018.09.018
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发表时间:
2018-12
期刊:
影响因子:
10.9
通讯作者:
Meng Miao;Songlin Zuo;Yunyang Zhao;Yong-fang Wang;Haian Xia;Chao Tan;Han Gao
Meng Miao;Songlin Zuo;Yunyang Zhao;Yong-fang Wang;Haian Xia;Chao Tan;Han Gao
中科院分区:
材料科学2区
文献类型:
--
作者:
Meng Miao;Songlin Zuo;Yunyang Zhao;Yong-fang Wang;Haian Xia;Chao Tan;Han Gao

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Graphite-like crystallites are the predominant structures that are strongly bonded together via amorphous carbons in biomass-based activated carbon. Here, we demonstrate a scalable process for efficiently decomposing biomass-based activated carbons into independent graphite-like crystallites with a high yield of 78 wt% by a selective oxidation scheme to rapidly break the amorphous carbon parts between graphite-like crystallites. The results show that the obtained graphite-like crystallite-based nanomaterials with tunable dimensions and morphologies has remarkable features, such as high water solubility and a strong tendency to self-assemble into a film structure.