A lab-on-a-molecule for anions in aqueous solution: using Kolbe electrolysis and radical methylation at iridium for sensing.
A lab-on-a-molecule for anions in aqueous solution: using Kolbe electrolysis and radical methylation at iridium for sensing.
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DOI：
10.1039/c2cc17731e
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发表时间：
2012-02
影响因子：
4.9
通讯作者：
M. Schmittel;Qinghai Shu
中科院分区：
文献类型：
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作者：
M. Schmittel;Qinghai Shu
铱配合物[（pq）（2）IrCl]（2）（1）在生理pH的水介质中被建立为定量操作的分子实验室。作为化学剂量计，1使用PL和ECL两个通道来检测氰化物和乙酸盐，前者经历亲核攻击，后者经历柯尔贝电解和自由基-金属结合。
Iridium complex [(pq)(2)IrCl](2) (1) is established as a quantitatively operating lab-on-a-molecule in aqueous media at physiological pH. Acting as a chemodosimeter, 1 uses two channels, PL and ECL, for the detection of cyanide and acetate, with the former undergoing nucleophilic attack and the latter Kolbe electrolysis and radical-metal combination.