Recyclable Hypervalent Iodine Reagents in Modern Organic Synthesis
Recyclable Hypervalent Iodine Reagents in Modern Organic Synthesis
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DOI：
10.1055/s-0041-1737909
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发表时间：
2022-03
期刊：
影响因子：
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通讯作者：
T. Dohi;V. Zhdankin;Ravi Kumar;Rimi Rimi-Rimi;Sakshi Soni;Bhawna Uttam;H. China
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文献类型：
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作者：
T. Dohi;V. Zhdankin;Ravi Kumar;Rimi Rimi-Rimi;Sakshi Soni;Bhawna Uttam;H. China
高价碘（HVI）试剂由于其毒性低、反应性温和、易于操作和可用性而作为多功能氧化剂受到广泛关注。尽管它们具有独特的反应性和其他有利的性质，但化学计量的HVI试剂与产生不可再循环的碘代芳烃作为废物/副产物的缺点相关。为了克服这些缺点，近年来已经建立了各种可回收的高价碘试剂的合成和利用。本文综述了各种可回收的非聚合物型、聚合物支载型、离子液体支载型和金属有机骨架（MOF）杂化的HVI试剂。1引言2聚合物负载的高价碘试剂2.1聚合物负载的高价碘（III）试剂2.2聚合物负载的高价碘（V）试剂3非聚合物可回收的高价碘试剂3.1非聚合物可回收的高价碘（III）试剂试剂3.2可回收的非聚合高价碘（V）试剂3.3氟高价碘试剂4离子液体/离子负载高价碘试剂5金属-有机骨架（MOF）杂化高价碘试剂6结论
Hypervalent iodine (HVI) reagents have gained much attention as versatile oxidants because of their low toxicity, mild reactivity, easy handling, and availability. Despite their unique reactivity and other advantageous properties, stoichiometric HVI reagents are associated with the disadvantage of generating non-recyclable iodoarenes as waste/co-products. To overcome these drawbacks, the syntheses and utilization of various recyclable hypervalent iodine reagents have been established in recent years. This review summarizes the development of various recyclable non-polymeric, polymer-supported, ionic-liquid-supported, and metal–organic framework (MOF)-hybridized HVI reagents.1 Introduction2 Polymer-Supported Hypervalent Iodine Reagents2.1 Polymer-Supported Hypervalent Iodine(III) Reagents2.2 Polymer-Supported Hypervalent Iodine(V) Reagents3 Non-Polymeric Recyclable Hypervalent Iodine Reagents3.1 Non-Polymeric Recyclable Hypervalent Iodine(III) Reagents3.2 Recyclable Non-Polymeric Hypervalent Iodine(V) Reagents3.3 Fluorous Hypervalent Iodine Reagents4 Ionic-Liquid/Ion-Supported Hypervalent Iodine Reagents5 Metal–Organic Framework (MOF)-Hybridized Hypervalent Iodine Reagents6 Conclusion