Iron-catalyzed dehydropolymerization: a convenient route to poly(phosphinoboranes) with molecular-weight control.
Iron-catalyzed dehydropolymerization: a convenient route to poly(phosphinoboranes) with molecular-weight control.
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DOI：
10.1002/anie.201411957
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发表时间：
2015-04
影响因子：
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通讯作者：
A. Schäfer;T. Jurca;J. Turner;J. R. Vance;Kajin Lee;V. A. Du;M. Haddow;G. Whittell;I. Manners
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文献类型：
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作者：
A. Schäfer;T. Jurca;J. Turner;J. R. Vance;Kajin Lee;V. A. Du;M. Haddow;G. Whittell;I. Manners
在铁催化膦硼烷加合物脱氢聚合反应中，催化剂的负载量是控制聚合物分子量的关键。研究表明，该反应通过链增长配位插入机制进行。
The catalyst loading is the key to control the molecular weight of the polymer in the iron-catalyzed dehydropolymerization of phosphine-borane adducts. Studies showed that the reaction proceeds through a chain-growth coordination-insertion mechanism.