The utility of indium in aqueous medium radical reactions
The utility of indium in aqueous medium radical reactions
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DOI：
10.1039/b316787a
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发表时间：
2004-01-01
影响因子：
3.2
通讯作者：
Naito, T
中科院分区：
文献类型：
--
作者：
Miyabe, H;Naito, T
铟介导的自由基反应在没有有毒的锡氢化物的情况下进行，提供了一种在水介质中形成碳-碳键的新方法。本文报道了在水介质中用铟作为自由基引发剂的实验结果。铟介导的串联反应也通过两个碳-碳键形成过程顺利进行，以制备各种类型的官能化环状化合物。
Indium-mediated radical reactions proceed in the absence of toxic tin hydride, providing a new carbon-carbon bond-forming method in aqueous media. Herein, the results of experiments to probe the utility of indium as a radical initiator in reactions in aqueous media are reported. The indium-mediated tandem reactions also proceed smoothly via two carbon-carbon bond-forming processes for the preparation of various types of functionalized cyclic compounds.