Transition metal carboxylate coordination polymers with amide-bridged polypyridine co-ligands: assemblies and properties
Transition metal carboxylate coordination polymers with amide-bridged polypyridine co-ligands: assemblies and properties
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DOI：
10.1039/c4ce02531h
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发表时间：
2015-01-01
期刊：
影响因子：
3.1
通讯作者：
Wang, Xiu-Li
中科院分区：
文献类型：
--
作者：
Zhang, Ju-Wen;Kan, Xiao-Min;Wang, Xiu-Li
配位聚合物可以通过金属离子与一种配体或混合配体的自组装而形成。羧酸根阴离子已被广泛用于构建具有不同结构和拓扑结构以及多种性能的金属有机CP。在金属羧酸盐体系中引入中性氮给体共配体是调节金属有机配合物结构和功能的有效策略。酰胺桥连多吡啶化合物作为一类中性的氮给体配体，在过去的十年中被引入到金属羧酸盐体系中。以羧酸根和酰胺桥联多吡啶为配体的金属有机配合物已被大量报道。因此，我们提出了最近的进展，过渡金属羧酸盐与酰胺桥聚吡啶的合作配体在这一重点。本文详细综述了它们的合成、结构、建筑影响因素和性能。这对合理设计和构建具有结构依赖性的酰胺桥连聚吡啶过渡金属羧酸盐聚合物具有重要意义。
Coordination polymers (CPs) can be formed by the self-assembly of metal ions and one kind of ligand or mixed ligands. Carboxylate anions have been extensively utilized to construct metal-organic CPs with diverse structures and topologies as well as versatile properties. The introduction of neutral nitrogen-donor co-ligands in such metal carboxylate system is an effective strategy for tuning the architectures and functionalities of metal-organic CPs. As a family of neutral nitrogen-donor co-ligands, amide-bridged polypyridine compounds have been introduced into such metal carboxylate system in the past decade. A large number of metal-organic CPs derived from the mixed ligands of carboxylate and amide-bridged polypyridine have been reported. Therefore, we present the recent developments of transition metal carboxylate CPs with amide-bridged polypyridine co-ligands in this highlight. We summarize their syntheses, structures, architectural influence factors and properties in detail. Such highlight may play a significant role in the rational design and construction of amide-bridged polypyridine-based transition metal carboxylate CPs with structure-dependent properties.