Reduction of Carboxylic Acid Derivatives Using Diphenylsilane in the Presence of a Rh–PPh3 Complex

Reduction of Carboxylic Acid Derivatives Using Diphenylsilane in the Presence of a Rh–PPh3 Complex
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DOI:
10.1246/bcsj.78.1856
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发表时间:
2005-10
影响因子:
4
通讯作者:
T. Ohta;M. Kamiya;Mami Nobutomo;Keisuke Kusui;I. Furukawa
T. Ohta;M. Kamiya;Mami Nobutomo;Keisuke Kusui;I. Furukawa
中科院分区:
化学3区
文献类型:
--
作者:
T. Ohta;M. Kamiya;Mami Nobutomo;Keisuke Kusui;I. Furukawa

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研究了在罗络合物存在下,硅烷对羧酸衍生物的还原作用。以[RhCl(CoD)]2/4PPPh3为催化剂,二苯基硅烷为催化剂,将羧酸酯还原为醇.
Reductions of carboxylic acid derivatives by silanes in the presence of rhodium complexes were studied. Carboxylic esters were reduced to alcohols by diphenylsilane catalyzed by [RhCl(cod)]2/4PPh3 ...