Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2·BPh4.

Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2·BPh4.
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DOI:
10.1039/c0cc04997b
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发表时间:
2011-02-14
期刊:
Chemical communications (Cambridge, England)
影响因子:
--
通讯作者:
Coppens P
Coppens P
中科院分区:
其他
文献类型:
--
作者:
Benedict JB;Makal A;Sokolow JD;Trzop E;Scheins S;Henning R;Graber T;Coppens P

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多色Laue技术已应用于Rh(I)双核配合物三重态激发态的100ps延迟同步加速器泵浦-探测实验。观测到的Rh-Rh距离0.154(13)ä的收缩比一系列理论计算所预测的要小,这一差异归因于晶格的约束效应。
The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump–probe experiments of the triplet excited state of a Rh(I) dinuclear complex. The observed contraction of the Rh–Rh distance of 0.154 (13) Å is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice.
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