THEORY OF SELF-ASSEMBLY OF HYDROCARBON AMPHIPHILES INTO MICELLES AND BILAYERS
THEORY OF SELF-ASSEMBLY OF HYDROCARBON AMPHIPHILES INTO MICELLES AND BILAYERS
复制标题
DOI：
10.1039/f29767201525
复制
发表时间：
1976-01-01
期刊：
影响因子：
--
通讯作者：
NINHAM, BW
中科院分区：
文献类型：
--
作者：
ISRAELACHVILI, JN;MITCHELL, DJ;NINHAM, BW
一个简单的理论，占许多观察到的物理性质的胶束，球状和棒状，和双层囊泡组成的离子或两性离子两亲物。与以往理论的主要区别在于认识和阐明了几何约束在自组装中的作用。热力学，相互作用自由能和几何形状的链接在一起的结果在一个一般的框架，允许扩展到更复杂的自组装问题。
A simple theory is developed that accounts for many of the observed physical properties of micelles, both globular and rod-like, and of bilayer vesicles composed of ionic or zwitterionic amphiphiles. The main point of departure from previous theories lies in the recognition and elucidation of the role of geometric constraints in self-assembly. The linking together of thermodynamics, interaction free energies and geometry results in a general framework which permits extension to more complicated self-assembly problems.