Carbonyl(η5-cyclo­penta­dienyl)(tri­methyl­silyl isocyanide)(tri­phenyl­phosphine)­iron(II) tri­fluoro­methane­sulfonate di­chloro­methane hemisolvate

Carbonyl(η5-cyclo­penta­dienyl)(tri­methyl­silyl isocyanide)(tri­phenyl­phosphine)­iron(II) tri­fluoro­methane­sulfonate di­chloro­methane hemisolvate
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羰基(η5-环戊二烯基)(三甲基甲硅烷基异氰)(三苯基膦)三氟甲磺酸铁(II)二氯甲烷半溶剂化物

DOI:
10.1107/s1600536805015308
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发表时间:
2005
影响因子:
--
通讯作者:
Mari Owaribe
Mari Owaribe
中科院分区:
--
文献类型:
--
作者:
H. Nakazawa;Masumi Itazaki;Mari Owaribe

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在标题化合物[Fe(C5 H5)(C4 H9 NSi)(C18 H15 P)(CO)](CF 3SO 3)·0.5CH2Cl2中,Fe Ⅱ原子与羰基、三苯基膦、三甲基硅基异腈和环戊二烯基配体配位,形成典型的平面粪便结构。Fe-C-N-Si排列几乎呈线性,Fe-C、C-N和N-Si键距分别为1.836(3)、1.162(4)和1.792(3)。    
In the title compound, [Fe(C5H5)(C4H9NSi)(C18H15P)(CO)](CF3SO3)·0.5CH2Cl2, the FeII atom is coordinated by carbonyl, tri­phenyl­phosphine, tri­methyl­silyl isocyanide and cyclo­penta­dienyl ligands in a typical piano-stool structure. The Fe—C—N—Si arrangement is almost linear and the Fe—C, C—N and N—Si bond distances are 1.836 (3), 1.162 (4) and 1.792 (3) A, respectively.
DOI: 10.1021/om0208319
发表时间: 2004
期刊: Organometallics
影响因子: 2.8
作者:
H. Nakazawa;Takafumi Kawasaki;K. Miyoshi;C. Suresh;N. Koga
通讯作者: H. Nakazawa;Takafumi Kawasaki;K. Miyoshi;C. Suresh;N. Koga