Aryl-triazole foldamers incorporating a pyridinium motif for halide anion binding in aqueous media.
Aryl-triazole foldamers incorporating a pyridinium motif for halide anion binding in aqueous media.
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DOI：
10.1039/c5cc10422j
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发表时间：
2016-03
影响因子：
4.9
通讯作者：
J. Shang;Wei Zhao;Xichen Li;Ying Wang;Hua Jiang
中科院分区：
文献类型：
--
作者：
J. Shang;Wei Zhao;Xichen Li;Ying Wang;Hua Jiang
由吡啶前体合成了含吡啶基序的芳基三唑低聚物。阴离子结合的研究表明，甲基化的吡啶单元可以显着提高卤素阴离子的亲和力的折叠低聚物，使折叠体能够在水溶液中结合卤素阴离子。
Aryl-triazole oligomers incorporating a pyridinium motif have been synthesized from their pyridine precursors. Anion binding studies show that methylation of the pyridine units can significantly enhance the halide anion affinities of the folded oligomers so that the foldamers are capable of binding halide anions in aqueous solutions.