N-Substituted 3(10H)-Acridones as Visible-Light, Water-Soluble Photocatalysts: Aerobic Oxidative Hydroxylation of Arylboronic Acids

N-Substituted 3(10H)-Acridones as Visible-Light, Water-Soluble Photocatalysts: Aerobic Oxidative Hydroxylation of Arylboronic Acids
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N-取代的 3(10H)-吖啶酮作为可见光、水溶性光催化剂:芳基硼酸的有氧氧化羟基化

DOI:
10.1021/acs.joc.7b00487
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发表时间:
2017
影响因子:
3.6
通讯作者:
Xu Qing-Long
Xu Qing-Long
中科院分区:
化学2区
文献类型:
--
作者:
Xie Hong-Yan;Han Li-Shuai;Huang Shan;Lei Xiantao;Cheng Yong;Zhao Wenfeng;Sun Hongbin;Wen Xiaoan;Xu Qing-Long

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我们公开了一种新型的水溶性光催化剂,其可以促进芳基硼酸的有氧氧化羟基化,以优异的产率提供酚。这种转化在环境友好的条件下使用可见光照射,即水溶性催化剂、无金属、绿色氧化剂、室温。
We disclosed a novel water-soluble photocatalyst that could promote aerobic oxidative hydroxylation of arylboronic acids to furnish phenols in excellent yields. This transformation uses visible-light irradiation under environmentally friendly conditions, that is, water-soluble catalyst, metal-free, green oxidant, room temperature.