Development of Solvay clusters of chemical reactions
Development of Solvay clusters of chemical reactions
复制标题
索尔维化学反应簇的发展
DOI：
10.1016/0009-2509(76)85009-9
复制
发表时间：
1976
影响因子：
4.7
通讯作者：
D. Rudd
中科院分区：
文献类型：
--
作者：
D. May;D. Rudd
索尔维纯碱工艺是用一组可行的化学反应取代不可行的反应的经典例子，涉及中间化学品的封闭循环使用。许多工业流程都基于这一策略。在此之前，没有任何原则来指导正确顺序的制定。在本文中，我们提出了一些实用的合成方法，可用于创建物理上可行的闭环化学反应序列。
The Solvay soda ash process is the classic example of the replacement of an infeasible reaction by a cluster of feasible chemical reactions involving the closed-cycle use of intermediate chemicals. Many industrial processes are based on this strategy. Previously, there had been no principles to guide the development of the proper sequence. In this paper we present certain practical methods of synthesis useful in creating thermodynamically feasible closed-cycle chemical reaction sequences.