Reversible Interconversion of C ? C and C ? N Multiple Bond Systems on Clusters
Reversible Interconversion of C ? C and C ? N Multiple Bond Systems on Clusters
复制标题
C 的可逆互变 ?
DOI：
10.1002/anie.198602791
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发表时间：
1986
影响因子：
--
通讯作者：
H. Vahrenkamp
中科院分区：
文献类型：
--
作者：
W. Bernhardt;C. V. Schnering;H. Vahrenkamp
在金属交换的条件下，基团可以支持有机配体区域内正向和反向的同一个反应。在如下图所示的序列中，首次观察到烷基炔-偏乙烯的自发转化。
Cluster moieties can be so conditioned by metal exchangethat they support one and the same reaction in the region of the organic ligands both in the forward and reverse direction. A spontaneous alkylidyne‐vinylidene transformation has been observed for the first time within the sequences of the type shown below.