X-Ray Crystal Structure of the First Quaternary 1-Bicyclo(1.1.1) pentane Salt. The Shortest “Nonbonding” Carbon-Carbon Interaction Documented.
X-Ray Crystal Structure of the First Quaternary 1-Bicyclo(1.1.1) pentane Salt. The Shortest “Nonbonding” Carbon-Carbon Interaction Documented.
复制标题
DOI：
10.1002/chin.199234051
复制
发表时间：
1992-08
期刊：
影响因子：
--
通讯作者：
J. Adcock;A. Gakh;Jonathan L. Pollitte;C. Woods
中科院分区：
文献类型：
--
作者：
J. Adcock;A. Gakh;Jonathan L. Pollitte;C. Woods
1中极短的非键合笼间距离是由于共振结构la和lc的贡献，每个共振结构都包含一个完整的（[1.1]）。1]螺桨烷型）Q-C3键，以及两个笼单元之间的短I-I-I距离。我们认为，这种取代的嗪盐作为创造具有不寻常电子性质的材料的可能成分，值得认真关注。
The extremely short nonbonding intercage distance in 1 is then due to contributionsfrom resonance structures la and lc, each of which contains one full ([1.1. 1] propellane-type) Q-C3 bond, as well as the short I—I—I distance between the two cage units. We believe that such substitutedazinium salts maywell deserve serious attention as possible components for the creation of ma-terials with unusual electronic properties.