Transition Metal Complex Catalyzed Photo- and Electrochemical (De)hydrogenations Involving C=O and C=N Bonds
Transition Metal Complex Catalyzed Photo- and Electrochemical (De)hydrogenations Involving C=O and C=N Bonds
复制标题
涉及 C=O 和 C=N 键的过渡金属配合物催化光和电化学（脱）氢化
DOI：
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发表时间：
2021
期刊：
影响因子：
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通讯作者：
Inke Siewert
中科院分区：
文献类型：
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作者：
Igor Fokin;Kai;Inke Siewert
摘要本文综述了羰基和亚胺的光催化和电化学脱氢和氢化反应。已探索的三个基本原则，以相互转换这样的部分与过渡金属配合物进行了详细讨论和基板范围进行了评估。此外，我们描述了一些一般的热力学和动力学方面的电和光化学驱动的反应。1引言2脱氢反应2.1使用高价金属物质的电化学脱氢2.2涉及金属氢化物物质的电化学脱氢2.3光化学驱动的脱氢3氢化反应3.1电化学方案3.2光化学方案4结论5缩写
Abstract Herein, we summarize the photo- and electrochemical protocols for dehydrogenation and hydrogenations involving carbonyl and imine functions. The three basic principles that have been explored to interconvert such moieties with transition metal complexes are discussed in detail and the substrate scope is evaluated. Furthermore, we describe some general thermodynamic and kinetic aspects of such electro- and photochemically driven reactions. 1 Introduction 2 Dehydrogenation Reactions 2.1 Electrochemical Dehydrogenations Using High-Valent Metal Species 2.2 Electrochemical Dehydrogenations Involving Metal Hydride species 2.3 Photochemically Driven Dehydrogenation 3 Hydrogenation Reactions 3.1 Electrochemical Protocols 3.2 Photochemical Protocols 4 Conclusion 5 Abbreviations