Oxidative transformation of thiols to disulfides promoted by activated carbon-air system

Oxidative transformation of thiols to disulfides promoted by activated carbon-air system
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DOI:
10.1016/j.tetlet.2010.10.070
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发表时间:
2010-12-22
影响因子:
1.8
通讯作者:
Eda, Kazuo
Eda, Kazuo
中科院分区:
化学4区
文献类型:
--
作者:
Hayashi, Masahiko;Okunaga, Ken-ichi;Eda, Kazuo

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在氧气(或空气)气氛下,在活性碳存在下,硫醇有效地氧化转化为二硫化物。这种氧化方法不仅适用于简单的芳香族和脂肪族硫醇等各种硫醇,而且还适用于3,4-二氢嘧啶-2(1H)-硫酮和N-Boc-L-半胱氨酸。(C)2010爱思唯尔有限公司。保留所有权利。
Efficient oxidative transformation of thiols to disulfides took place in the presence of activated carbon under an oxygen (or air) atmosphere. The present oxidation method is available not only for a variety of thiols such as simple aromatic and aliphatic thiols but also for 3,4-dihydropyrimidin-2(1H)-thiones and N-Boc-L-cysteine. (C) 2010 Elsevier Ltd. All rights reserved.