Syntheses of homologous, tritium‐labelled photoaffinity analogs of the natural juvenile hormones JH I, JH II, and JH III
Syntheses of homologous, tritium‐labelled photoaffinity analogs of the natural juvenile hormones JH I, JH II, and JH III
复制标题
天然保幼激素 JH I、JH II 和 JH III 的同源氚标记光亲和类似物的合成
DOI：
10.1002/jlcr.2580280108
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发表时间：
1990
影响因子：
1.8
通讯作者：
G. Prestwich
中科院分区：
文献类型：
--
作者：
I. Ujváry;W. Eng;G. Prestwich
Enantiomerically enriched (≥92% e.e.) tritium-labelled diazoacetate photoaffinity analogs EBDA and EHDA (each 58 Ci/mmol) and EFDA (14 Ci/mmol) were prepared from the corresponding tritiated juvenile hormone (JH) homologs JH I, JH II, and JH III in two steps. Selective reduction of the ester group and subsequent acylation gave the target compounds.
