Reversible anion binding in aqueous solution at a cationic heptacoordinate lanthanide centre: selective bicarbonate sensing by time-delayed luminescence

Reversible anion binding in aqueous solution at a cationic heptacoordinate lanthanide centre: selective bicarbonate sensing by time-delayed luminescence
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DOI:
10.1039/a804255a
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发表时间:
1998-08-21
影响因子:
4.9
通讯作者:
Peacock, RD
Peacock, RD
中科院分区:
化学2区
文献类型:
--
作者:
Dickins, RS;Gunnlaugsson, T;Peacock, RD

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Reversible displacement of up to two metal bound water molecules at a coordinately unsaturated, cationic lanthanide centre is signalled by increases in the luminescence intensity or lifetime of the emissive lanthanide: selective chelation of hydrogencarbonate is consistent with emission spectroscopic, ESMS and CPL measurements.