Asymmetric hydroamination of non-activated carbon-carbon multiple bonds
Asymmetric hydroamination of non-activated carbon-carbon multiple bonds
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DOI：
10.1039/b711126f
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发表时间：
2007-01-01
影响因子：
4
通讯作者：
Schulz, Emmanuelle
中科院分区：
文献类型：
--
作者：
Aillaud, Isabelle;Collin, Jacqueline;Schulz, Emmanuelle
综述了催化氢胺化反应中碳氮键的不对称选择性形成。所有实施例涉及含有非活性碳-碳多重键的底物，所述非活性碳-碳多重键通过分子内或分子间反应转化。结构不同的络合物已经提供了具有高对映选择性的含氮化合物/杂环。
The catalysed enantioselective formation of carbon-nitrogen bonds by the hydroamination reaction is reviewed. All examples deal with substrates containing non-activated carbon-carbon multiple bonds which are transformed either via intramolecular or intermolecular reactions. Structurally different complexes already provided nitrogen containing compounds/heterocycles with high enantioselectivities.