Solvent extraction mechanism of pertechnetate with tetraphenylarsonium chloride

Solvent extraction mechanism of pertechnetate with tetraphenylarsonium chloride
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DOI:
10.1007/bf02039717
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发表时间:
1994-03
影响因子:
1.6
通讯作者:
T. Omori;Y. Muraoka;H. Suganuma
T. Omori;Y. Muraoka;H. Suganuma
中科院分区:
化学4区
文献类型:
--
作者:
T. Omori;Y. Muraoka;H. Suganuma

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在25 ℃、离子强度为1.0的条件下,用氯化四苯胂(TPAC)的氯仿溶液从氯化物水溶液中萃取高锝酸盐。确定了控制TPAC分布平衡的基本参数。根据TPAC的分配机理建立了高锝酸盐的萃取行为。
A systematic study of extraction of pertechnetate with tetraphenylarsonium chloride (TPAC) in chloroform from aqueous chloride solutions has been carried out at 25°C at ionic strength of 1.0. Fundamental parameters governing the distribution equilibrium of TPAC were determined. Extraction behavior of pertechnetate was established on the basis of the distribution mechanism of TPAC.