1-Phenyl-5-{[2-(trimethyl-sil-yl)eth-yl]sulfon-yl}-1H-tetra-zole.
1-Phenyl-5-{[2-(trimethyl-sil-yl)eth-yl]sulfon-yl}-1H-tetra-zole.
复制标题
1-苯基-5- {[[2-（三甲基 - 硅基）乙基]硫酸} -1H-TETRA-ZOLE。
DOI：
10.1107/s1600536811030492
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发表时间：
2011-09-01
期刊：
影响因子：
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通讯作者：
Hiersemann M
中科院分区：
文献类型：
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作者：
Tymann D;Nelson B;Strohmann C;Preut H;Hiersemann M
The title compound, C12H18N4O2SSi, was synthesized to be employed in a Julia–Kocieński olefination. In the molecule, the dihedral angle between the phenyl ring and the tetrazole ring is 41.50 (5)°. The significantly longer Si—C(methylene) bond [1.8786 (13) Å] and the shortened adjacent C—C bond [1.5172 (18) Å], as well as the significant deviation of the corresponding Si—C—C angle [114.16 (9)°] from the ideal tetrahedral angle, can be attributed to the β-effect of silicon. In the crystal, molecules are held together by van der Waals interactions.
