EFFECT OF NONCLASSICAL POLARIZATION OF Na+ AND K+ ON THE STABILITY OF SOIL COLLOIDAL PARTICLES IN SUSPENSION

EFFECT OF NONCLASSICAL POLARIZATION OF Na+ AND K+ ON THE STABILITY OF SOIL COLLOIDAL PARTICLES IN SUSPENSION
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Na、K非经典极化对悬浮土壤胶体颗粒稳定性的影响

DOI:
10.1142/s0218625x18500191
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发表时间:
2017-08
影响因子:
1.1
通讯作者:
Li Hang
Li Hang
中科院分区:
材料科学4区
文献类型:
--
作者:
Ding Wu-Quan;He Jia-Hong;Wang Lei;Liu Xin-Min;Li Hang

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土壤胶体的研究至关重要,因为土壤胶体颗粒的稳定性是环境领域研究人员感兴趣的重要过程。吸附的阳离子(Na⁺和K⁺)的强非经典极化降低了……
The study of soil colloids is essential because the stability of soil colloidal particles are important processes of interest to researchers in environmental fields. The strong nonclassical polarization of the adsorbed cations (Na+ and K+) decreased the electric field and the electrostatic repulsion between adjacent colloidal particles. The decrease of the absolute values of surface potential was greater for K+ than for Na+. The lower the concentration of Na+ and K+ in soil colloids, the greater the electrostatic repulsion between adjacent colloidal particles. The net pressure and the electrostatic repulsion was greater for Na+ than for K+ at the same ion concentration. For K+ and Na+ concentrations higher than 50mmol L−1 or 100 mmol L−1, there was a net negative (or attractive) pressure between two adjacent soil particles. The increasing total average aggregation (TAA) rate of soil colloids with increasing Na+ and K+ concentrations exhibited two stages: the growth rates of TAA increased rapidly at first and then increased slowly and eventually almost negligibly. The critical coagulation concentrations of soil colloids in Na+ and K+ were 91.6mmol L−1 and 47.8mmol L−1, respectively, and these were similar to the concentrations at the net negative pressure.
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