Lanthanide(II) and -(III) porphyrinogens - rational synthesis and derivatisation of mononuclear, alkali-metal-free lanthanide(II) and -(III) meso-octaalkylporphyrinogen complexes
Lanthanide(II) and -(III) porphyrinogens - rational synthesis and derivatisation of mononuclear, alkali-metal-free lanthanide(II) and -(III) meso-octaalkylporphyrinogen complexes
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DOI：
10.1002/ejic.200300965
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发表时间：
2004-05
影响因子：
2.3
通讯作者：
Jun Wang;A. Dick;M. Gardiner;B. Yates;E. J. Peacock;B. Skelton;Allan H. White
中科院分区：
文献类型：
--
作者：
Jun Wang;A. Dick;M. Gardiner;B. Yates;E. J. Peacock;B. Skelton;Allan H. White
通过反式-N，N′-二甲基化修饰镧系卟啉原络合物中的卟啉原骨架，得到结构和组成非常简单的Sm II和Sm III衍生物，并且易于进行高度可控的进一步反应化学。合成了Sm Ⅱ双（四氢呋喃）加合物、Sm Ⅲ氯化物和双（三甲基硅基）酰胺配合物，并通过元素分析、~ 1H和~（13）C NMR谱和X射线晶体结构测定进行了表征。© Wiley-VCH Verlag GmbH & Co. KGaA，69451魏因海姆，德国，2004。
Modifying the porphyrinogen framework in lanthanide porphyrinogen complexes by trans-N,N′-dimethylation results in Sm II and Sm III derivatives that are remarkably simple in structure and formulation, and are amenable to highly controllable further reaction chemistry. The Sm II bis(tetrahydrofuran) adduct, Sm III chloride and bis(trimethylsilyl)amide complexes have been synthesised and characterised by elemental analysis, 1H and 13C NMR spectroscopy and X-ray crystal structure determinations. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.