Toward a 'reagent-free' synthesis - Tandem enzymatic and electrochemical methods for increased effective mass yield (EMY)
Toward a 'reagent-free' synthesis - Tandem enzymatic and electrochemical methods for increased effective mass yield (EMY)
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DOI：
10.1039/a901397k
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发表时间：
1999-04-01
期刊：
影响因子：
9.8
通讯作者：
Brammer, LE
中科院分区：
文献类型：
--
作者：
Hudlicky, T;Frey, DA;Brammer, LE
比较了环己-5-烯-1R，2S，3R，4 R-四醇（conduritol C）和环己-5-烯-1S，2 R，3R，4 R-四醇（conduritol F）的几种合成途径;分析了每种合成途径的废物最小化效果。最新的合成，在这份手稿中报道，结合酶促转化与电化学方法。定义并说明了“有效质量产额”（EMY）的概念。
Several synthetic pathways to cyclohex-5-ene-1R,2S,3R,4R-tetrol (conduritol C) and cyclohex-5-ene-1S,2R,3R,4R- tetrol (conduritol F) are compared; each is analyzed for effectiveness of waste minimization. The latest synthesis, reported in this manuscript, combines enzymatic transformations with electrochemical methods. The concept of "effective mass yield" (EMY) is defined and illustrated.