Ammonia Chemiresistor Sensor Based on Poly(3-Hexylthiophene) Film Oxidized by Nitrosonium Hexafluorophosphate

Ammonia Chemiresistor Sensor Based on Poly(3-Hexylthiophene) Film Oxidized by Nitrosonium Hexafluorophosphate
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DOI:
10.1246/cl.2012.1569
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发表时间:
2012-12-05
期刊:
影响因子:
1.6
通讯作者:
Pan, Ge-Bo
Pan, Ge-Bo
中科院分区:
化学4区
文献类型:
--
作者:
Li, Yan;Liu, Yong-Qiang;Pan, Ge-Bo

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以六氟磷酸亚硝基氧化的聚(3-己基噻吩)薄膜为基础,研制了一种氨化学电阻传感器。该传感器对氨反应良好,但对多种有机蒸气不敏感。检出限估计约为0.22 ppm。氨与双极化子之间的氧化还原反应归因于传感器信号。
An ammonia chemiresistor sensor is demonstrated on the basis of a poly(3-hexylthiophene) film oxidized by nitrosonium hexafluorophosphate. The sensor gave a good response to ammonia, but it was insensitive to a variety of organic vapors. The detection limit was estimated to be ca. 0.22 ppm. The redox reaction between ammonia and bipolarons was attributed to the sensor signals.