CONVERSION OF NORMAL-BUTANOL ACETONE MIXTURES TO C-1-C-10 HYDROCARBONS ON HZSM-5 TYPE ZEOLITES
CONVERSION OF NORMAL-BUTANOL ACETONE MIXTURES TO C-1-C-10 HYDROCARBONS ON HZSM-5 TYPE ZEOLITES
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DOI：
10.1021/ie00004a007
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发表时间：
1992-04-01
影响因子：
4.2
通讯作者：
CANIZARES, P
中科院分区：
文献类型：
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作者：
COSTA, E;AGUADO, J;CANIZARES, P
研究了正丁醇/丙酮混合物转化为1-C-10烃的反应。用自制的不同硅铝比的ZSM-5型沸石分子筛作为催化剂。采用硅铝比为36的HZSM-5沸石，以30wt%的钠基蒙脱石为粘结剂，可获得最好的改性效果。考察了操作条件(空时、温度、压力)和原料水分含量对反应转化率的影响。
The conversion of n-butanol/acetone mixtures to C1-C-10 hydrocarbons has been studied. ZSM-5 type zeolites with different Si/Al ratios, synthesized in our laboratories, were used as catalysts. The best results were obtained with a HZSM-5 zeolite (Si/Al = 36), using a 30 wt % sodium montmorillonite as binder. The effect of operating conditions (space time, temperature, and pressure) and the influence of water content of the feed on the reaction conversion have been studied.