Topochemical Conversion of a Hydrogen-Bonded Three-Dimensional Network into a Covalently Bonded Framework.
Topochemical Conversion of a Hydrogen-Bonded Three-Dimensional Network into a Covalently Bonded Framework.
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DOI：
10.1002/(sici)1521-3773(19980504)37:8
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发表时间：
1998-05
影响因子：
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通讯作者：
J. Ranford;J. Vittal;Daqing Wu
中科院分区：
文献类型：
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作者：
J. Ranford;J. Vittal;Daqing Wu
热脱水促进氢键二聚复合物 [{Zn(sala)(H2 O)2 }2 ]⋅2 H2 O (H2 (sala)=N-(2-羟基苄基)-L-丙氨酸) 的拓扑化学转化，生成共价 [{Zn(sala)}n ]。 X射线晶体学揭示氢键在此过程中起着关键作用（见右侧的部分结构）。
Thermal dehydration promotes the topochemical conversion of the hydrogen-bonded dimeric complex [{Zn(sala)(H2 O)2 }2 ]⋅2 H2 O (H2 (sala)=N-(2-hydroxybenzyl)-L-alanine) to generate covalent [{Zn(sala)}n ]. X-ray crystallography reveals that hydrogen bonding plays a key role in this process (see the partial structure on the right).