Highly dispersed Ru clusters toward an efficient and durable hydrogen oxidation reaction

Highly dispersed Ru clusters toward an efficient and durable hydrogen oxidation reaction
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DOI:
10.1039/d2cc04591e
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发表时间:
2022-09-27
影响因子:
4.9
通讯作者:
Liu, Xijun
Liu, Xijun
中科院分区:
化学2区
文献类型:
--
作者:
Meng, Ge;Cao, Huijie;Liu, Xijun

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负载在氮掺杂空心碳球上的Ru团簇在碱性介质中对氢氧化反应(HOR)和H2 O2燃料电池性能表现出显著的活性和耐久性。理论模拟表明,钌团簇赋予一个philically有利的HOR动力学和最佳的氢吸附亲和力。
Here, Ru clusters supported on nitrogen-doped hollow carbon spheres show a remarkable activity and durability toward the hydrogen oxidation reaction (HOR) and H-2-O-2 fuel cell performance in alkaline media. Theoretical simulations indicate that Ru clusters endow a thermodynamically favourable HOR kinetics and an optimal hydrogen adsorption affinity.