Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations
Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations
复制标题
DOI：
10.1021/ja109103t
复制
发表时间：
2011-02-09
影响因子：
15
通讯作者：
Rosi, Nathaniel L.
中科院分区：
文献类型：
--
作者：
An, Jihyun;Shade, Chad M.;Rosi, Nathaniel L.
采用Tb 3+、Sm 3+、Eu 3+、Yb 3+离子交换法合成了发光金属有机骨架材料（MOFs）Ln（3+）@bio-MOF-1，并对其物理化学性质进行了研究。我们证明，生物MOF-1封装和敏化可见光和近红外发射镧系阳离子在水溶液中。
Luminescent metal-organic frameworks (MOFs), Ln(3+)@bio-MOF-1, were synthesized via post-synthetic cation exchange of bio-MOF-1 with Tb3+, Sm3+, Eu3+, or Yb3+, and their photophysical properties were studied. We demonstrate that bio-MOF-1 encapsulates and sensitizes visible and near-infrared emitting lanthanide cations in aqueous solution.