Silole Silylene Route to NHC-Stabilized Fused 1-Silabicycles and 1,1-Spirobisiloles
Silole Silylene Route to NHC-Stabilized Fused 1-Silabicycles and 1,1-Spirobisiloles
复制标题
Silole Silene 转化为 NHC 稳定的稠合 1-Silabicycles 和 1,1-Spirobisiloles 的路线
DOI：
10.1002/asia.201700050
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发表时间：
2017
影响因子：
4.1
通讯作者：
Cui Chunming
中科院分区：
文献类型：
--
作者：
Li Tianhao;Zhang Jianying;Cui Chunming
The reaction of an NHC‐stabilized silole silylene (1, 1‐silacyclopentadienylidene) with one equivalent of internal acetylenes resulted in the formation of NHC‐stabilized 1‐silabicyclo[3.2.0]hepta‐1,3,6‐trienes, which subsequently reacted with one equivalent of the acetylene to yield an aryl‐substituted 1,1′‐spirobisilole (SBS). The SBSs can also be prepared by reaction of the NHC‐stabilized silole silylene1with two equivalents of the acetylenes in good yields. The electronic structures of these SBSs have been studied by UV/Vis and emission spectroscopy, as well as DFT calculations.
