Are the orientation and bond strength of the RCO2(-)···M link key factors for ultrafast electron transfers?
Are the orientation and bond strength of the RCO2(-)···M link key factors for ultrafast electron transfers?
复制标题
RCO2(-)·M连接的取向和键合强度是超快电子转移的关键因素吗？
DOI：
10.1039/c5cc06779k
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发表时间：
2015
影响因子：
4.9
通讯作者：
P. Harvey
中科院分区：
文献类型：
--
作者：
P. Luo;P. Karsenti;G. Brisard;B. Marsan;P. Harvey
[pd3(2+)]···mcp和[pd3(2+)]···dcp··[pd3(2+)]([pd3(2+)]*→mcp或dcp)中的光致电子转移是超快的(<；85fs)，这表明在含卟啉的DSC中不需要有强的配位键或弯曲的几何构型来获得快速的电子注入。
The photo-induced electron transfers in the "straight up" ionic assemblies [Pd3(2+)]···MCP and [Pd3(2+)]···DCP···[Pd3(2+)] ([Pd3(2+)]* → MCP or DCP) are ultrafast (<85 fs) indicating that it is not necessary to have a strong coordination bond or a bent geometry to obtain fast electron injection in porphyrin-containing DSSCs.
Zn-卟啉-TiO_2 电极的光生载流子动力学 电荷复合对太阳能电池性能的关键作用
影响因子：
2.9
作者：
今堀博;姜舜徹;林宏暢;治田充貴;倉田博基;磯田正二;Sophie E.Canon;Yingyot Infahsaeng;Arunkwnar Kathiravan;Torbjom Pascher;Pavel Chabera;Arkaay P.Yartsev;Villy Sundshtim
通讯作者：
Villy Sundshtim