Modulable cooperativity in a valence tautomeric complex functionalized with branched alkyl chains.
Modulable cooperativity in a valence tautomeric complex functionalized with branched alkyl chains.
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DOI：
10.1039/c001568g
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发表时间：
2010-05
影响因子：
4.9
通讯作者：
D. Kiriya;Kohei Nakamura;S. Kitagawa;Ho‐Chol Chang
中科院分区：
文献类型：
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作者：
D. Kiriya;Kohei Nakamura;S. Kitagawa;Ho‐Chol Chang
具有支链、不对称烷基链的钴/二氧杂烯烃配合物的功能化促进了非合作价和合作价互变异构，根据结晶度的不同，它们分别与热力学上有利的晶体-熔体和动力学上产生的玻璃-熔体相变同步。
Functionalization of a cobalt/dioxolene complex with branched, asymmetric alkyl chains promotes non-cooperative and cooperative valence tautomerisms synchronized with thermodynamically favoured crystal-to-melt and kinetically generated glass-to-melt phase transitions, respectively, depending on the degree of crystallinity.