A NEW MOLECULAR SUPERCONDUCTOR, (BEDT-TTF)2(I3)1−x(AuI2)x(x<0.02)

A NEW MOLECULAR SUPERCONDUCTOR, (BEDT-TTF)2(I3)1−x(AuI2)x(x<0.02)
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一种新型分子超导体,(BEDT-TTF)2(I3)1−x(AuI2)x(x<0.02)

DOI:
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发表时间:
1986
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通讯作者:
W. Sasaki
W. Sasaki
中科院分区:
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文献类型:
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作者:
H. Kobayashi;R. Kato;A. Kobayashi;Y. Nishio;K. Kajita;W. Sasaki

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以(n-C4 H8)4 Ni 3和(n-C4 H9)4 NAuI 2为支持电解质,采用电化学方法制备了一种基于BEDT-TTF分子的新型分子超导体。超导转变发生在3.6K的环境压力下。X射线衍射分析表明,该体系属于准正交晶系,晶格常数为a=10.076(2),B=33.853(5),c=4.964(1)。
A new molecular superconductor based on BEDT-TTF molecule was prepared electrochemically by using the mixed supporting electrolyte, (n-C4H9)4NI3 and (n-C4H8)4NAuI2. The superconducting transition takes place at ambient pressure at 3.6 K. X-Ray diffraction patterns show that the system can be approximately assigned to a pseudo orthorhombic one with the lattice constants of a=10.076(2), b=33.853(5), c=4.964(1) A.