Recent Advances in Titanium Radical Redox Catalysis
Recent Advances in Titanium Radical Redox Catalysis
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DOI：
10.1021/acs.joc.9b02465
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发表时间：
2019-11-15
影响因子：
3.6
通讯作者：
Lin, Song
中科院分区：
文献类型：
--
作者：
McCallum, Terry;Wu, Xiangyu;Lin, Song
利用单电子氧化还原事件的新催化策略为化学家解决合成问题提供了有用的工具。在这种情况下，Ti为反应发现提供了与晚期过渡金属互补的机会。在环氧化物还原功能化的基础工作之后，最近的方法进展大大扩展了钛自由基化学的曲目。本文概述了钛自由基催化的最新进展，重点介绍了钛自由基氧化还原接力和双催化等创新的催化策略。
New catalytic strategies that leverage single-electron redox events have provided chemists with useful tools for solving synthetic problems. In this context, Ti offers opportunities that are complementary to late transition metals for reaction discovery. Following foundational work on epoxide reductive functionalization, recent methodological advances have significantly expanded the repertoire of Ti radical chemistry. This Synopsis summarizes recent developments in the burgeoning area of Ti radical catalysis with a focus on innovative catalytic strategies such as radical redox-relay and dual catalysis.