ABSOLUTE ELECTRONEGATIVITY AND HARDNESS - APPLICATION TO INORGANIC-CHEMISTRY
ABSOLUTE ELECTRONEGATIVITY AND HARDNESS - APPLICATION TO INORGANIC-CHEMISTRY
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DOI：
10.1021/ic00277a030
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发表时间：
1988-02-24
影响因子：
4.6
通讯作者：
PEARSON, RG
中科院分区：
文献类型：
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作者：
PEARSON, RG
（1 + A）/2和17=（7-A）/2用于计算大量阳离子、原子、自由基和分子的实验值。所得值被证明是在良好的协议与化学行为，无论是作为酸碱字符和作为化学硬度或柔软度。阴离子由其相应的自由基建模，并指出了局域软度的重要性，离域阴离子。给出了使用的列表值在排序和数值计算中的应用。
(/+ A)/2 and 17=(7—A)/2, are used to calculate experimental values for a large number of cations, atoms, radicals, and molecules. The resulting values are shown to be in good agreement with chemical behavior, both as to acid-base character and as to chemical hardness or softness. Anions are modeled by their corresponding radicals, and the importance of local softness,, for delocalized anions is pointed out. Applications of the use of tabulated values of, both for rank ordering and in numerical calculation, are given.