Cu(II)-catalyzed selective aerobic oxidation of alcohols under mild conditions
Cu(II)-catalyzed selective aerobic oxidation of alcohols under mild conditions
复制标题
DOI：
10.1021/jo060837y
复制
发表时间：
2006-09-01
影响因子：
3.6
通讯作者：
Ragauskas, Arthur J.
中科院分区：
文献类型：
--
作者：
Jiang, Nan;Ragauskas, Arthur J.
在DMSO中建立了由乙酰胺- tempo /Cu(ClO4)(2)/TMDP/DABCO组成的高效四组分体系，用于室温好氧醇氧化。在最佳条件下，各种醇均能以优异的收率转化为相应的醛类或酮类。新开发的催化系统还可以循环使用三次，而没有任何明显的催化活性损失。
An efficient four-component system consisting of acetamido-TEMPO/Cu(ClO4)(2)/TMDP/DABCO in DMSO has been developed for room-temperature aerobic alcohol oxidation. Under the optimal conditions, various alcohols could be converted into their corresponding aldehydes or ketones in good to excellent yields. The newly developed catalytic system could also be recycled and reused for three runs without any significant loss of catalytic activity.