Research Progress in the Direct Synthesis of Dimethyl Carbonate from CO2 and Methanol
Research Progress in the Direct Synthesis of Dimethyl Carbonate from CO2 and Methanol
复制标题
CO2与甲醇直接合成碳酸二甲酯的研究进展
DOI：
10.1007/s10563-012-9140-5
复制
发表时间：
2012-09-01
影响因子：
3
通讯作者：
Liu, Zhiming
中科院分区：
文献类型：
--
作者：
Cao, Yunxia;Cheng, Hangxin;Liu, Zhiming
以二氧化碳和甲醇为原料直接合成碳酸二甲酯（DMC）是减少温室气体排放和利用碳资源的一种有吸引力的方法。综述了近年来CO2和甲醇直接合成DMC的研究进展，重点介绍了催化剂体系，包括有机金属化合物催化剂、碱催化剂、乙酸催化剂、金属氧化物和负载型金属氧化物催化剂、杂多酸催化剂和光催化剂。此外，还介绍了超临界体系、离子液体体系、电化学体系、膜反应器和腈水化反应在直接合成DMC中的应用。最后，提出了该领域未来的研究方向。
The direct synthesis of dimethyl carbonate (DMC) from CO2 and methanol is one attractive way for the reduction of greenhouse gas emission and the utilization of carbon resources. Recent progress in the direct synthesis of DMC from CO2 and methanol is reviewed with the focus on the catalyst systems, including organic metal compounds catalyst, base catalyst, acetate catalyst, metal oxide and supported metal oxide catalysts, heteropolyacid catalyst and photocatalyst. Moreover, the application of supercritical system, ionic liquid system, electrochemical system, membrane reactor and nitriles hydration in the direct synthesis of DMC are also introduced. Finally, future research direction in this area is proposed.