Beilstein Journal of Organic Chemistry Beilstein Journal of Organic Chemistry Beilstein Journal of Organic Chemistry the First Salen-type Ligands Derived from 3',5'-diamino-3',5'-dideoxythymidine and -dideoxyxylothymidine and Their Corresponding Copper(ii) Complexes

Beilstein Journal of Organic Chemistry Beilstein Journal of Organic Chemistry Beilstein Journal of Organic Chemistry the First Salen-type Ligands Derived from 3',5'-diamino-3',5'-dideoxythymidine and -dideoxyxylothymidine and Their Corresponding Copper(ii) Complexes
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Beilstein 有机化学杂志 Beilstein 有机化学杂志 Beilstein 有机化学杂志 第一个源自 3,5-二氨基-3,5-二脱氧胸苷和 β-二脱氧胸苷及其相应铜(ii)配合物的 Salen 型配体

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通讯作者:
K. Pohle
K. Pohle
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作者:
D. Koth;M. Gottschaldt;H. Görls;K. Pohle

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背景:已知有许多核苷金属配合物。根据观察,只有极少数的人揭示了他们的中心离子是由他们的分子的糖部分协调。通过螯合单元在糖部分的羟基的区域和立体特异性交换提高了其络合能力,并且应该获得一类新的手性配体。
Background: There are many nucleoside metal complexes known. According to observations made, only very few of them reveal their central ion to be coordinated by the sugar part of their molecules. The regio-and stereosspecific exchange of the hydroxyl groups at the sugar moiety by chelating units improves its complexation ability and should give access to a new class of chiral ligands.