Self-enhancement of CO reversible absorption accompanied by phase transition in protic chlorocuprate ionic liquids for effective CO separation from N-2
Self-enhancement of CO reversible absorption accompanied by phase transition in protic chlorocuprate ionic liquids for effective CO separation from N-2
复制标题
质子氯铜酸盐离子液体中 CO 可逆吸收伴随相变的自我增强,可有效分离 N2 中的 CO
DOI:
10.1039/c9cc00089e
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发表时间:
2019
影响因子:
4.9
通讯作者:
Hu Xing Bang
中科院分区:
文献类型:
--
作者:
Tu Zhuo Heng;Zhang Yi Yang;Wu You Ting;Hu Xing Bang
An efficient strategy for the high-capacity capture of CO is reported, and a phase change in protic chlorocuprate ionic liquids (PCILs) from liquid to solid is found during CO absorption. The highest CO capacity is 0.96 molCO molIL−1, being at least 150 times higher than that in [BMIM][PF6]. Both absorption and membrane permeation reveal that the PCILs are potential for the selective separation of CO from N2.