Ullmann reaction in tetraethyl orthosilicate: a novel synthesis of triarylamines and diaryl ethers.

Ullmann reaction in tetraethyl orthosilicate: a novel synthesis of triarylamines and diaryl ethers.
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DOI:
10.1039/b706449g
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发表时间:
2007-07
影响因子:
4.9
通讯作者:
Yuanhong Zhao;Yun-Song Wang;Hongwei Sun;Liang Li;Hongbin Zhang
Yuanhong Zhao;Yun-Song Wang;Hongwei Sun;Liang Li;Hongbin Zhang
中科院分区:
化学2区
文献类型:
--
作者:
Yuanhong Zhao;Yun-Song Wang;Hongwei Sun;Liang Li;Hongbin Zhang

文献摘要

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报道了三芳胺和二芳基醚的新合成方法;该过程的一个特点是在原硅酸四乙酯中形成无配体的铜催化的 C-N 和 C-O 键。
A novel synthesis of triarylamines and diaryl ethers is reported; a feature of this process is the ligand-free copper-catalysed C-N and C-O bond formation in tetraethyl orthosilicate.