Coordination-Network-Based Ionic Plastic Crystal for Anhydrous Proton Conductivity
Coordination-Network-Based Ionic Plastic Crystal for Anhydrous Proton Conductivity
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DOI：
10.1021/ja301875x
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发表时间：
2012-05-09
影响因子：
15
通讯作者：
Kitagawa, Susumu
中科院分区：
文献类型：
--
作者：
Horike, Satoshi;Umeyama, Daiki;Kitagawa, Susumu
合成了由质子化咪唑和负离子一维链磷酸锌组成的离子配位网络。该化合物在晶格中具有高度移动的离子，并表现为离子塑性晶体。动态行为提供了在130摄氏度无湿度下2.6 × 10（-4）S cm（-1）的质子传导率。
An ionic coordination network consisting of protonated imidazole and anionic one-dimensional chains of Zn2+ phosphate was synthesized. The compound possesses highly mobile ions in the crystal lattice and behaves as an ionic plastic crystal. The dynamic behavior provides a proton conductivity of 2.6 X 10(-4) S cm(-1) at 130 degrees C without humidity.